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Physical and Chemical Characteristics

In addition to the basic elastomer descriptions, it is helpful to have information on the important physical and chemical properties of various elastomer compounds. This information helps provide a clear picture of how physical and chemical properties interact with the elastomer which allows for proper selection of an effective seal material. The more basic physical properties that have to be considered are listed below.

In some of the sections below, it mentions how various factors can alter the properties of rubber materials. Low temperatures cause reversible hardening of compounds, high temperatures may cause  reversible and non-reversible changes of many kinds, and exposure to fluids can effect all the properties of a rubber material. Besides these more-or-less obvious effects, there are many additional ways in which the properties of a compound may be modified which may create differences in results from two different laboratories. Knowledge of some of these pitfalls may avoid misunderstandings.

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    Hardness

    Throughout the seal industry, the Shore A type durometer scale, manufactured by a variety of manufacturers, is the standard instrument used to measure the hardness of most rubber compounds.
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    Tensile Strength

    Tensile strength is one quality assurance measurement used to insure compound uniformity.
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    Modulus

    Modulus, as used in rubber terminology, refers to stress at a predetermined elongation, usually 100%.
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    Elongation

    Elongation is defined as the increase in length, expressed numerically, as a percent of initial length. It is generally reported as ultimate elongation, the increase over the original dimension at break
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    Resistance to Fluid

    The chemical effect of the fluid on the seal is of prime importance. The fluid must not alter the operational characteristics or reduce the life expectancy of the seal significantly.
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    Volume Change

    Volume change is the increase or decrease of the volume of an elastomer after it has been in contact with a fluid, measured in percent (%).
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    O-Ring Compression Force

    O-ring compression force is the force required to compress an O-ring the amount necessary to maintain an adequate sealing line of contact.
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    High Temperature Effects

    All rubber is subject to deterioration at high temperature. Volume change and compression set are both greatly influenced by heat. The first effect of increased temperature is to soften the compound.
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    Low Temperature Effects

    Low temperature testing is imperative to ensuring sufficient seal performance in industries where low temperature operating conditions are common. 
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    Coefficient of Thermal Expansion

    Coefficient of linear expansion is the ratio of the change in length per °C to the length at 0°C.
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    Abrasion Resistance

    Abrasion resistance is a general term that indicates the wear resistance of a compound.
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    Permeability

    Permeability is the tendency of gas to pass or diffuse through the elastomer.
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    Corrosion

    Corrosion is the result of chemical action of a fluid and/or the elastomer compound upon the metal surfaces of the seal gland cavity.
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    Laboratory Compression Set

    Compression set is generally determined in air aging and reported as the percent of deflection by which the elastomer fails to recover after a fixed time under specified squeeze and temperature.
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Parker Hannifin
O-Ring & Engineered Seals
2360 Palumbo Drive
Lexington, KY 40509
Ph: 859-269-2351
Fax: 859-335-5128
oesmailbox@parker.com
www.parkerorings.com